Microwave-assisted synthesis of 4-(2,2'-bithiophen-5-yl)-5-phenylpyrimidine derivatives as sensors for detection of nitroaromatic explosives

Microwave-assisted synthesis of 4-(2,2'-bithiophen-5-yl)-5-phenylpyrimidine derivatives as sensors for detection of nitroaromatic explosives = Микроволновый синтез производных 4-(2,2'-битиофенил-5-ил)-5-фенилпиримидина и их применение в качестве сенсоров нитроароматических взрывчатых веществ / E. V. Verbitskiy, E. M. Cheprakova, A. A. Baranova, K. O. Khokhlov, K. I. Ludovik, G. L. Rusinov, O. N. Chupakhin, V. N. Charushin // Chemistry of Heterocyclic Compounds. - 2016. - Vol. 52, № 11. - С. 904-909. - Bibliogr. : p. 909 (27 ref.).

Год: 

2016

Связанные персоналии: 

Нет

Рубрики: 

  • Химические науки

Вид издания: 

  • статья из журнала

Коллекции:
Нет

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Аннотация

Аннотация

A reaction sequence involving microwave-assisted Suzuki cross-coupling steps and bromination with N-bromosuccinimide was used to synthesize 4-{4-[4',5'-bis(4-diphenylaminophenyl)-3'-hexyl-2,2'-bithiophen-5-yl]pyrimidin-5-yl}benzonitrile. The optical properties of the obtained compound were studied to evaluate it for possible applications as a sensor of nitroaromatic compounds in acetonitrile solutions and gas phase