Solvent-free reaction of 1,2,4-triazine-5-carbonitriles with 4-(cyclohex-1-en-1-yl)morpholine. unexpected decyanation in addition to classical aza-Diels–Alder reaction

Solvent-free reaction of 1,2,4-triazine-5-carbonitriles with 4-(cyclohex-1-en-1-yl)morpholine. unexpected decyanation in addition to classical aza-Diels–Alder reaction / D. S. Kopchuk, A. F. Khasanov, N. V. Chepchugov [et al.] // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2017. - Vol. 53, № 1. - P. 99-102.

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2017

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Аннотация

The reaction of 1,2,4-triazine-5-carbonitriles with 4-(cyclohex-1-en-1-yl)morpholine under solventfree conditions has been found to follow two pathways: aza-Diels–Alder reaction and unexpected decyanation of the initial nitriles. The scope of the revealed decyanation reaction has been roughly estimated.